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Place Louis Pasteur 1/L4.01.02
1348 Louvain-la-Neuve
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Raphaël Robiette
Maître de recherche FNRS
Professeur
Professional experience
2003-2004 Postdoc University of California at Los Angeles
2004-2005 Postdoc University of Bristol
2005-2009 Chargé de recherches F.R.S.-FNRS Université catholique de Louvain
2009- F.R.S.-FNRS Research Fellow and Professor Université catholique de Louvain
- Diploma
Year Label Educational Organization 1996 Candidat en sciences chimiques Université catholique de Louvain 1998 Licencié en sciences chimiques Université catholique de Louvain 1999 Diplômé d'études approfondies en chimie moléculaire Université catholique de Louvain 2003 Docteur en sciences Université catholique de Louvain
- Organic synthesis
- Physical organic chemistry
- Medicinal chemistry
- Theoretical chemistry
2024
Vogl, Lukas S. ; Mayer, Peter ; Robiette, Raphaël ; Waser, Mario. Chiral Isochalcogenourea‐Catalysed Enantioselective (4+2) Cycloadditions of Allenoates. In: Angewandte Chemie International Edition, Vol. 63, no.2, p. e202315345 (2024). doi:10.1002/anie.202315345.
2024
Janssens, Julien ; De Roose, Madeline ; Jacquemin, Alexis ; Vanhosmael, Thomas ; Delbrassinne, Arnaud ; Collard, Laurent ; Robiette, Raphaël. One-Carbon Homologation of Knoevenagel Adducts: Enantioselective Access to Benzhydryl Derivatives. In: The Journal of Organic Chemistry, Vol. 89, no.10, p. 7270-7274 (2024). doi:10.1021/acs.joc.4c00057.
2024
Bensaida, Ali ; Mahaut, Damien ; Tumanov, Nikolay ; Wouters, Johan ; Champagne, Benoît ; Vanthuyne, Nicolas ; Robiette, Raphaël ; Berionni, Guillaume. Reactivity and Steric Parameters from 2D to 3D Bulky Pyridines : Increasing Steric Demand at Nitrogen with Chiral Azatriptycenes. In: Angewandte Chemie International Edition, Vol. 63, p. e202407503 (2024). doi:10.1002/anie.202407503.
2024
Hu, Lei ; Chakraborty, Sayandip ; Tumanov, Nikolay ; Wouters, Johan ; Robiette, Raphaël ; Berionni, Guillaume. Regulating iminophosphorane PN bond reactivity through geometric constraints with cage-shaped triarylphosphines. In: Chemical Communications, Vol. 60, p. 7073-7076 (2024). doi:10.1039/d4cc01868k.
2023
Delbrassinne, Arnaud ; Takam Mba, Boris Junior ; Collard, Laurent ; Robiette, Raphaël. One‐Carbon Homologation of α,β‐Unsaturated Aldehydes: Access to α‐Tertiary β,γ‐Unsaturated Aldehydes. In: European Journal of Organic Chemistry, Vol. 26, no. 40, p. e2023007 (2023). doi:10.1002/ejoc.202300765.
2022
Chenot, Cécile ; Robiette, Raphaël ; Collin, Sonia. First evidence of the glutathione S-conjugate of 3-sulfanylheptanol in green malt: discrepancy with the ubiquitous 5- and 6-C analogues. In: Institute of Brewing & Distilling. Brewing & Distilling Directory, Vol. 128, no.2, p. 43-51 (2022). doi:10.1002/jib.690.
2022
Chenot, Cécile ; Haest, Sébastien ; Robiette, Raphaël ; Collin, Sonia. Thiol S-Conjugate Profiles: A Comparative Investigation on Dual Hop and Grape Must with Focus on Sulfanylalkyl Aldehydes and Acetates Adducts. In: American Society of Brewing Chemists. Journal, Vol. /, no.1, p. 1-11 (2022). doi:10.1080/03610470.2021.2015560.
2021
Kassin, Victor-Emmanuel H. ; Morodo, Romain ; Toupy, Thomas ; Jacquemin, Isaline ; Van Hecke, Kristof ; Robiette, Raphaël ; Monbaliu, Jean-Christophe M.. A modular, low footprint and scalable flow platform for the expedient α-aminohydroxylation of enolizable ketones. In: Green Chemistry, Vol. 23, no.6, p. 2336-2351 (2021). doi:10.1039/d0gc04395h.
2021
Caillé, Julien ; Robiette, Raphaël. Cycloaddition of Cyclopropanes for the Elaboration of Medium-sized Carbocycles. In: Organic & Biomolecular Chemistry, (2021). doi:10.1039/d1ob00838b (Accepté/Sous presse).
2021
Delbrassinne, Arnaud ; Richald, Maximilien ; Janssens, Julien ; Robiette, Raphaël. Divergent Rearrangements of Vinylcyclopropane into Skipped Diene and Cyclopentene: Mechanism, Scope, and Limitations. In: European Journal of Organic Chemistry, Vol. 2021, no.20, p. 2862-2868 (2021). doi:10.1002/ejoc.202100430.
2021
Hu, Lei ; Mahaut, Damien ; Tumanov, Nikolay ; Wouters, Johan ; Collard, Laurent ; Robiette, Raphaël ; Berionni, Guillaume. Sterically hindered ortho-substituted phosphatriptycenes as configurationally stable P-chirogenic triarylphosphines. In: Dalton Transactions, Vol. 50, no.14, p. 4772-4777 (2021). doi:10.1039/d1dt00816a.
2020
Morelle, Axel ; Caruano, Joséphine ; Feledziak, Marion ; Michaux, Catherine ; Perpète, Eric ; Muccioli, Giulio ; Marchand-Brynaert, Jacqueline ; Robiette, Raphaël. β-lactams to act on the endocannabinoid system. In: Chimie Nouvelle, Vol. 134, p. 41 (2020).
2019
Hu, Lei ; Mahaut, Damien ; Tumanov, Nikolay ; Wouters, Johan ; Robiette, Raphaël ; Berionni, Guillaume. Complementary Synthetic Approaches toward 9-Phosphatriptycene and Structure–Reactivity Investigations of Its Association with Sterically Hindered Lewis Acids. In: The Journal of Organic Chemistry, Vol. 84, no.17, p. 11268-11274 (2019). doi:10.1021/acs.joc.9b01570.
2019
Chenot, Cécile ; Robiette, Raphaël ; Collin, Sonia. First Evidence of the Cysteine and Glutathione Conjugates of 3-Sulfanylpentan-1-ol in Hop (Humulus lupulus L.). In: Journal of Agricultural and Food Chemistry, Vol. 67, no.14, p. 4002-4010 (2019). doi:10.1021/acs.jafc.9b00225.
2019
Scheinok, Samantha ; Driesschart, Benoit ; d'Hose, Donatienne ; Sonveaux, Pierre ; Robiette, Raphaël ; Gallez, Bernard. Synthesis and characterization of a 5-membered ring cyclic hydroxylamine coupled to triphenylphosphonium to detect mitochondrial superoxide by EPR spectrometry.. In: Free radical research, Vol. 53, no. 11-12, p. 1135-1143 (2019). doi:10.1080/10715762.2019.1692137.
2019
Richald, Maximilien ; Delbrassinne, Arnaud ; Robiette, Raphaël. Unexpected Vinylcyclopropane Rearrangement: New Strategies toward Skipped Dienes Using Sulfonium Ylides : Unexpected Vinylcyclopropane Rearrangement: New Strategies toward Skipped Dienes Using Sulfonium Ylides. In: European Journal of Organic Chemistry, Vol. 2019, no.23, p. 3779-3782 (2019). doi:10.1002/ejoc.201900720.
2018
Clergue, Sébastien ; Rousseau, Olivier ; Delaunay, Thierry ; Dequirez, Geoffroy ; Tran, Trieu-Van ; El Aakchioui, Soumia ; Barozzino Consiglio, Gabriella ; Robiette, Raphaël. Asymmetric Sulfur-Ylide-Mediated Formal [4+1]-Annulation Reaction: Scope and Mechanism. In: Chemistry - A European Journal, Vol. 24, no.44, p. 11417-11425 (2018). doi:10.1002/chem.201801874.
2018
Kankolongo Ntumba, Joséphine ; Tshiongo, Christian ; Mifundu, Michel ; Robiette, Raphaël ; Taba, Kalulu. Effective Antimalarial Activities of α-Hydroxy Diynes Isolated from Ongokea gore . In: Planta Medica, Vol. 84, no.11, p. 806-812 (2018). doi:10.1055/s-0043-124974.
2018
Frédéric, Christophe J.-M. ; Cornil, Jérôme ; Vandamme, Mathilde ; Dumitrescu, Lidia ; Tikad, Abdellatif ; Robiette, Raphaël ; Vincent, Stéphane P.. Highly (Z)-Diastereoselective Synthesis of Trifluoromethylated exo-Glycals via Photoredox and Copper Catalysis. In: Organic Letters, Vol. 20, no.21, p. 6769-6773 (2018). doi:10.1021/acs.orglett.8b02891.
2018
Eitzinger, Andreas ; Zielke, Katharina ; Widhalm, Michael ; Robiette, Raphaël ; Waser, Mario. Syntheses of Highly Functionalized Spirocyclohexenes by Formal [4+2] Annulation of Arylidene Azlactones with Allenoates. In: Asian Journal of Organic Chemistry, Vol. 7, no.8, p. 1620-1625 (2018). doi:10.1002/ajoc.201800275.
2018
Fan, Yang ; Tiffner, Maximilian ; Schörgenhumer, Johannes ; Robiette, Raphaël ; Waser, Mario ; Kass, Steven R.. Synthesis of Cyclic Organic Carbonates Using Atmospheric Pressure CO2 and Charge-Containing Thiourea Catalysts. In: The Journal of Organic Chemistry, Vol. 83, no.17, p. 9991-10000 (2018). doi:10.1021/acs.joc.8b01374.
2017
Meisinger, Nicole ; Roiser, Lukas ; Monkowius, Uwe ; Himmelsbach, Markus ; Robiette, Raphaël ; Waser, Mario. Asymmetric Synthesis of 2,3-Dihydrobenzofurans by a [4+1] Annulation Between Ammonium Ylides and In Situ Generatedo-Quinone Methides. In: Chemistry: A European Journal, Vol. 23, no.21, p. 5137-5142 (2017). doi:10.1002/chem.201700171.
2017
Cibaka, Marie-Lucie Kankolongo ; Tran, Thi Thu Hang ; Gros, Jacques ; Robiette, Raphaël ; Collin, Sonia. Investigation of 2-Sulfanylethyl Acetate Cysteine-S-Conjugate as a Potential Precursor of Free Thiols in Beer. In: Journal of the American Society of Brewing Chemists, Vol. 75, no.3, p. 228-235 (2017). doi:10.1094/asbcj-2017-3276-01.
2017
Novacek, Johanna ; Robiette, Raphaël ; Waser, Mario. On the origin of the stereoselectivity in chiral amide-based ammonium ylide-mediated epoxidations. In: Monatshefte für Chemie : an international journal of chemistry, Vol. 148, no.1, p. 77-81 (2017). doi:10.1007/s00706-016-1866-8.
2017
Depré, Dominique ; Vermeulen, Wim A. A. ; Lang, Yolande ; Dubois, Jean ; Vandevivere, Jan ; Vandermeersch, Jeremy ; Huang, Longchuan ; Robiette, Raphaël. Origin of the E/Z Selectivity in the Synthesis of Tetrasubstituted Olefins by Wittig Reaction of α-Fluorophosphonium Ylides: An Explanation for the Low Stereoselectivity Observed in Reactions of α-Alkoxy Aldehydes. In: Organic Letters, Vol. 19, no.6, p. 1414-1417 (2017). doi:10.1021/acs.orglett.7b00344.
2017
Ntumba, J. K. ; Mulula, A. ; Kashishi, K. T. ; Mifundu, M. N. ; Robiette, Raphaël ; Taba, K. M.. Physicochemical Properties of Diacetylenic Light Fuel Oil from Congolese Oleaginous PlantOngokea gore(Hua) Pierre. In: Journal of Applied Chemistry, Vol. 2017, p. 1-6 (2017). doi:10.1155/2017/7176317.
2016
Kankolongo Cibaka, Marie-Lucie ; Decourrière, Laura ; Lorenzo-Alonso, Celso josé ; Bodart, Etienne ; Robiette, Raphaël ; Collin, Sonia. 3‐Sulfanyl-4-methylpentan-1-ol in Dry-Hopped beers: first evidence of glutathione S‐Conjugates in hop (Humulus lupulus L.). In: Journal of Agricultural and Food Chemistry, Vol. 64, no.45, p. 8572–8582 (2016). doi:10.1021/acs.jafc.6b03788.
2016
Robiette, Raphaël ; Tran, Trieu-Van ; Aggarwal, Varinder K. ; Harvey, Jeremy N.. Activation of the SN2 Reaction by Adjacent π Systems: The Critical Role of Electrostatic Interactions and of Dissociative Character. In: Journal of the American chemical society, Vol. 138, no. 3, p. 734-737 (2016). doi:10.1021/jacs.5b11402.
2016
Roiser, Lukas ; Robiette, Raphaël ; Waser, Mario. Benzylic Ammonium Ylide Mediated Epoxidations. In: Synlett : accounts and rapid communications in synthetic organic chemistry, Vol. 27, no.13, p. 1963-1968 (2016). doi:10.1055/s-0035-1562344.
2016
Caruano, Joséphine ; Muccioli, Giulio ; Robiette, Raphaël. Biologically active γ-lactams: synthesis and natural sources. In: Organic & Biomolecular Chemistry, Vol. 14, no.43, p. 10134-10156 (2016). doi:10.1039/C6OB01349J.
2016
Novacek, Johanna ; Roiser, Lukas ; Zielke, Katharina ; Robiette, Raphaël ; Waser, Mario. Towards a General Understanding of Carbonyl-Stabilised Ammonium Ylide-Mediated Epoxidation Reactions. In: Chemistry: A European Journal, Vol. 22, no.32, p. 11422-11428 (2016). doi:10.1002/chem.201602052.
2015
Pichler, Mathias ; Novacek, Johanna ; Robiette, Raphaël ; Poscher, Vanessa ; Himmelsbach, Markus ; Monkowius, Uwe ; Müller, Norbert ; Waser, Mario. Asymmetric Syntheses of Three-Membered Heterocycles Using Chiral Amide-Based Ammonium Ylides. In: Organic & Biomolecular Chemistry, Vol. 13, no. not applicable, p. 2092-2099 (2015). doi:10.1039/C4OB02318H.
2015
Rousseau, Olivier ; Delaunay, Thierry ; Dequirez, Geoffroy ; Tran, Trieu-Van ; Robeyns, Koen ; Robiette, Raphaël. Formal Asymmetric (4+1) Annulation Reaction between Sulfur Ylides and 1,3-Dienes. In: Chemistry: A European Journal, Vol. 21, no. 37, p. 12899-12902. doi:10.1002/chem.201502579.
2015
Ntumba Kankolongo, Joséphine ; Collard, Laurent ; Taba, Kalulu ; Robiette, Raphaël. Isolation of a Series of Fatty Acid Components of Ongokea Gore Seed (Isano) Oil and Their Detailed Structural Analysis. In: Lipids, . doi:10.1007/s11745-014-3984-6 (Accepté/Sous presse).
2014
Caruano, Joséphine ; Feledziak, Marion ; Labar, Geoffray ; Michaux, Catherine ; Perpete, Eric ; Muccioli, Giulio ; Robiette, Raphaël ; Marchand-Brynaert, Jacqueline. (S)-1-(Pent-4’-enoyl)-4-(hydroxymethyl)-azetidin-2-one derivatives as inhibitors of human fatty acid amide hydrolase (hFAAH): synthesis, biological evaluation and molecular modelling. In: Journal of Enzyme Inhibition and Medicinal Chemistry, Vol. 29, no. /, p. 654-662 (2014). doi:10.3109/14756366.2013.837900.
2014
Ntumba Kankolongo, Joséphine ; Taba, Kalulu ; Robiette, Raphaël. L’huile d’Ongokea Gore (isano) : Analyse de sa composition chimique et valorisation par dérivatisation. In: Chimie Nouvelle, Vol. 2014, no. 117, p. 12-20 (2014).
2014
Rousseau, Olivier ; Delaunay, Thierry ; Robiette, Raphaël. Synthesis of Monosubstituted 1,1-Dicarbonyl Ester 1,3-Dienes. In: Synlett : accounts and rapid communications in synthetic organic chemistry, Vol. 2014, p. 519-522 (2014). doi:10.1055/s-0033-1340468 (Accepté/Sous presse).
2013
Robiette, Raphaël ; Caruano, Joséphine ; Van Den Berge, Emilie ; Rousseau, Olivier ; Tran, Trieu-Van. Comprendre les réactions pour mieux les développer et les utiliser. In: Chimie Nouvelle, Vol. 113, no. [2], p. 18-20 (2013).
2013
Van Den Berge, Emilie ; Robiette, Raphaël. Development of a Regioselective N-Methylation of (Benz)imidazoles Providing the More Sterically Hindered Isomer.. In: Journal of Organic Chemistry, Vol. 78, no.23, p. 12220-12223 (1/11/2013). doi:10.1021/jo401978b.
2013
Nizet, Sabrina ; Gros, Jacques ; Peeters, Florence ; Chaumont , Sophie ; Robiette, Raphaël ; Collin, Sonia. First Evidence of the Production of Odorant Polyfunctional Thiols by Bottle Refermentation. In: American Society of Brewing Chemists. Journal, Vol. 71, no.1 , p. 15-22 (2013). doi:10.1094/ASBCJ-2013-0117-01.
2013
Mathieu, Véronique ; Van Den Berge, Emilie ; Ceusters, Justine ; Konopka, Tomasz ; Cops, Antonin ; Bruyère, Céline ; Pirker, Christine ; Tran, Trieu-Van ; Kiss, Robert ; Robiette, Raphaël ; Berger, Walter ; Serteyn, Didier. New 5-aryl-1H-imidazoles display in vitro antitumor activity against apoptosis-resistant cancer models, including melanomas, through mitochondrial targeting. In: Journal of Medicinal Chemistry, Vol. 56, p. 6626-6637. doi:10.1021/jm400287v.
2013
Robiette, Raphaël ; Pospíšil, J.. On the Origin of E/Z Selectivity in the Modified Julia Olefination - Importance of the Elimination Step. In: European Journal of Organic Chemistry, Vol. 2013, no.5, p. 836-840 (2013). doi:10.1002/ejoc.201201634.
2013
Villemin, Elise ; Robeyns, Koen ; Robiette, Raphaël ; Herent, Marie-France ; Marchand-Brynaert, Jacqueline. Polycyclic phosphonic acid derivatives obtained by a [4+2] cycloaddition strategy using phosphonodienes. In: Tetrahedron, Vol. 69, no. 3, p. 1138-1147 (2013). doi:10.1016/j.tet.2012.11.059.
2012
Driesschaert, Benoît ; Robiette, Raphaël ; Le Duff, Cécile S. ; Collard, Laurent ; Robeyns, Koen ; Gallez, Bernard ; Marchand-Brynaert, Jacqueline. Configurationally stable tris(tetrathioaryl)methyl molecular propellers. In: European Journal of Organic Chemistry, Vol. 2012, no. 33, p. 6517-6525 (2012). doi:10.1002/ejoc.201200801.
2012
Billard, François ; Robiette, Raphaël ; Pospisil, Jiri. Julia-Kocienski Reaction-Based 1,3-Diene Synthesis: Aldehyde-Dependent (E,E/E,Z)-Selectivity. In: The Journal of Organic Chemistry, Vol. 77, no. 14, p. 6358-6364 (16/07/2012). doi:10.1021/jo300929a.
2012
Dive, Georges ; Robiette, Raphaël ; Ahenel, Aurélie ; Ndong, M. ; Meier, C. ; Desouter-Lecomte, Michele. Laser control in open quantum systems: Preliminary analysis towards the Cope rearrangement control in methyl-cyclopentadienylcarboxylate dimer. In: Theoretical Chemistry Accounts, Vol. 131, no.1, p. 1236 (June 2012). doi:10.1007/s00214-012-1236-5.
2012
Pospisil, Jiri ; Robiette, Raphaël ; Sato, Hitoshi ; Debrus, Kevin. Practical synthesis of β-oxo benzo[d]thiazolyl sulfones: Scope and limitations. In: Organic & Biomolecular Chemistry, Vol. 10, no. 6, p. 1225-1234. doi:10.1039/C1OB06510F.
2011
Driesschaert, Benoît ; Robiette, Raphaël ; Lucaccioni, Fabio ; Gallez, Bernard ; Marchand-Brynaert, Jacqueline. Chiral properties of tetrathiatriarylmethyl spin probes. In: Chemical communications, Vol. 47, no. 16, p. 4793-4795 (2011). doi:10.1039/c1cc10988j.
2011
Villemin, Elise ; Elias, Benjamin ; Robiette, Raphaël ; Robeyns, Koen ; Herent, Marie-France ; Habib Jiwan, Jean-Louis ; Marchand-Brynaert, Jacqueline. Novel phosphonated bicyclic frameworks from Diets-Alder reaction as chelating agents of di- and trivalent metal cations. In: Tetrahedron Letters, Vol. 52, no. 40, p. 5140-5144 (2011). doi:10.1016/j.tetlet.2011.07.116.
2011
Van Den Berge, Emilie ; Pospisil, Jiri ; trieu-van, tran ; Collard, Laurent ; Robiette, Raphaël. Planar Chirality of Imidazole-Containing Macrocycles - Understanding and Tuning Atropisomerism. In: European Journal of Organic Chemistry, Vol. 2011, p. 6649-6655 (2011). doi:10.1002/ejoc.201100805.
2010
Robiette, Raphaël ; Tran, Trieu-Van ; Cordi, Alex ; Tinant, Bernard ; Marchand-Brynaert, Jacqueline. A Practical Synthesis of 1,2-Nitroamines by Michael Addition of N-Nucleophiles to Nitroalkenes. In: Synthesis : journal of synthetic organic chemistry, , no. 18, p. 3138-3142 (2010). doi:10.1055/s-0030-1258176.
2010
Robert, François ; Naik, Anil ; Hidara, Florence ; Tinant, Bernard ; Robiette, Raphaël ; Wouters, Johan ; Garcia, Yann. Engineering Solid-State Molecular Switches: N-Salicylidene N-Heterocycle Derivatives. In: European Journal of Organic Chemistry, , no. 4, p. 621-637 (2010). doi:10.1002/ejoc.200901175.
2010
Nshimyumukiza, Prosper ; Van Den Berge, Emilie ; Delest, Bruno ; Mijatovic, Tatjana ; Kiss, Robert ; Marchand-Brynaert, Jacqueline ; Robiette, Raphaël. Synthesis and biological evaluation of novel imidazole-containing macrocycles. In: Tetrahedron, Vol. 66, no. 25, p. 4515-4520 (2010). doi:10.1016/j.tet.2010.04.070.
2009
Monbaliu, Jean-Christophe ; Robiette, Raphaël ; Peeters, Daniel ; Marchand-Brynaert, Jacqueline. (R)-4-phenyloxazolidin-2-thione: an efficient chiral auxiliary for [4+2] cycloaddition of 1-aminodiene and activated phosphonodienophiles. In: Tetrahedron Letters, Vol. 50, no. 12, p. 1314-1317 (2009).
2009
Robert, François ; Naik, Anil ; Tinant, Bernard ; Robiette, Raphaël ; Garcia, Yann. Insights into the Origin of Solid-State Photochromism and Thermochromism of N-Salicylideneanils: The Intriguing Case of Aminopyridines.. In: Chemistry: A European Journal, Vol. 15, no. 17, p. 4327-42 (2009). doi:10.1002/chem.200801932.
2008
Robiette, Raphaël ; Marchand-Brynaert, Jacqueline. Diastereoselective synthesis of vinylcyclopropanes from dienes and sulfur ylides. In: Synlett : accounts and rapid communications in synthetic organic chemistry, no. 4, p. 517-520 (2008). doi:10.1055/s-2008-1032080.
2008
Delest, Bruno ; Nshimyumukiza, Prosper ; Fasbender, Olivier ; Tinant, Bernard ; Marchand-Brynaert, Jacqueline ; Darro, Francis ; Robiette, Raphaël. Divergent and regioselective synthesis of 1,2,4- and 1,2,5-trisubstituted imidazoles.. In: The Journal of organic chemistry, Vol. 73, no. 17, p. 6816-23 (2008). doi:10.1021/jo801256b.
2008
Howells, Dean ; Robiette, Raphaël ; Fang, Guang Y. ; Knowles, Luke S. ; Woodrow, Michael D. ; Harvey, Jeremy ; Aggarwal, Varinder K.. Reactions of silyl-stabilised sulfur ylides with organoboranes: enantioselectivity, mechanism, and understanding. In: Organic & Biomolecular Chemistry, Vol. 6, no. 7, p. 1185-1189 (2008). doi:10.1039/b718496d.
2007
Broustal, Garance ; Ariza, Xavier ; Campagne, Jean-Marc ; Garcia, Jordi ; Georges, Yohan ; Marinetti, Angela ; Robiette, Raphaël. A stereoselective approach to 1,3-amino alcohols protected as cyclic carbamates: Kinetic vs. thermodynamic control. In: European Journal of Organic Chemistry, , no. 26, p. 4293-4297 (2007). doi:10.1002/ejoc.200700503.
2007
Robiette, Raphaël ; Aggarwal, Varinder K. ; Harvey, Jeremy. Mechanism of the Morita-Baylis-Hillman reaction: A computational investigation. In: Journal of the American Chemical Society, Vol. 129, no. 50, p. 15513-15525 (2007). doi:10.1021/ja0717865.
2006
Robiette, Raphaël ; Conza, M ; Aggarwal, Varinder K.. Delineation of the factors governing reactivity and selectivity in epoxide formation from ammonium ylides and aldehydes. In: Organic & Biomolecular Chemistry, Vol. 4, no. 4, p. 621-623 (2006). doi:10.1039/b516926g.
2006
Aggarwal, Varinder K. ; Charmant, Jonathan P.H. ; Fuentes, Daniel ; Harvey, Jeremy ; Hynd, George ; Ohara, Diasuke ; Picoul, Willy ; Robiette, Raphaël ; Vasse, Jean-Luc ; Winn, Caroline L.. Highly enantioselective synthesis of glycidic amides using camphor-derived sulfonium salts. Mechanism and applications in synthesis. In: Journal of the American chemical society, Vol. 128, no. 6, p. 2105-2114 (2006). doi:10.1021/ja0568345.
2006
Robiette, Raphaël ; Fang, G.Y. ; Harvey, J.N. ; Aggarwal, V.K.. Is phenyl a good migrating group in the rearrangement of organoborates generated from sulfur ylides?. In: Chemical Communications, Vol. 1, no. 7, p. 741-743 (2006). doi:10.1039/b514987h.
2006
Robiette, Raphaël. Mechanism and diastereoselectivity of aziridine formation from sulfur ylides and imines: a computational study.. In: The Journal of organic chemistry, Vol. 71, no. 7, p. 2726-34 (2006). doi:10.1021/jo052559t.
2006
Harvey, Jeremy ; Aggarwal, Varinder K. ; Bathelt, C.M. ; Carreon-Macedo, J.L. ; Gallagher, T. ; Holzmann, N. ; Mulholland, A.J. ; Robiette, Raphaël. QM and QM/MM studies of selectivity in organic and bioorganic chemistry. In: Journal of Physical Organic Chemistry, Vol. 19, no. 8-9, p. 608-615 (2006). doi:10.1002/poc.1030.
2006
Robiette, Raphaël ; Richardson, J ; Aggarwal, Varinder K. ; Harvey, Jeremy. Reactivity and selectivity in the Wittig reaction: A computational study. In: Journal of the American chemical society, Vol. 128, no. 1, p. 2394-2409 (2006). doi:10.1021/ja056650q.
2005
Robiette, Raphaël ; Defacqz, N ; Peeters, Daniel ; Marchand-Brynaert, Jacqueline. A novel strategy towards aminophosphonic derivatives based on the Diels-Alder cycloaddition: Experimental and theoretical approaches. In: Current Organic Synthesis, Vol. 2, no. 4, p. 453-477 (2005). doi:10.2174/157017905774322668.
2005
Aggarwal, Varinder K. ; Harvey, Jeremy N. ; Robiette, Raphaël. On the importance of leaving group ability in reactions of ammonium, oxonium, phosphonium, and sulfonium ylides. In: Angewandte Chemie (International Edition), Vol. 44, no. 34, p. 5468-5471 (2005). doi:10.1002/anie.200501526.
2005
Robiette, Raphaël ; Richardson, J ; Aggarwal, VK ; Harvey, JN. On the origin of high E selectivity in the Wittig reaction of stabilized ylides: Importance of dipole-dipole interactions. In: Journal of the American chemical society, Vol. 127, no. 39, p. 13468-13469 (2005). doi:10.1021/ja0539589.
2005
Boulanger, ML ; Leyssens, Tom ; Robiette, Raphaël ; Peeters, Daniel. Theoretical approach of steric effects in the Diels-Alder reaction. In: Journal of Molecular Structure: THEOCHEM, Vol. 731, no. 1-3, p. 101-106 (2005). doi:10.1016/j.theochem.2005.07.005.
2004
Tinant, Bernard ; Defacqz, Nathalie ; Robiette, Raphaël ; Touillaux, Roland ; Marchand-Brynaert, Jacqueline. Stereochemistry and conformation of amido-phosphonocyclohexene derivatives, assigned by NMR and X-ray diffraction analyses. In: Phosphorus, Sulfur and Silicon and the Related Elements, Vol. 179, no. 2, p. 389-402 (2004). doi:10.1080/10426500490262522.
2003
Robiette, Raphaël ; Dekoker-Malengreau, A ; Marchand-Brynaert, Jacqueline. A study of the alkylation and rearrangement products of chiral 1,3-oxazolidine- and thiazolidine-2-thiones. In: Heterocycles, Vol. 60, no. 3, p. 523-+ (2003). doi:10.3987/COM-02-9653.
2003
Peeters, Daniel ; Leyssens, Tom ; Robiette, Raphaël. Analyse de la réorganisation électronique dans les molécules en réaction. In: Chimie Nouvelle, Vol. 82, no. -, p. 91-95 (2003).
2003
Tinant, Bernard ; Robiette, Raphaël ; Marchand-Brynaert, Jacqueline. Crystal structure of (S)-3-(Z-1 ',3 '-butadienyl)-4-phenylthiazoline-2-one, C13H13NOS, a chiral 1-amino-diene useful in Diels-Alder cycloaddition reactions. In: Zeitschrift fuer Kristallographie - New Crystal Structures, Vol. 218, no. 4, p. 475-476 (2003). doi:10.1524/ncrs.2003.218.4.475.
2003
Robiette, Raphaël ; Cheboub-Benchaba, Karima ; Peeters, Daniel ; Marchand-Brynaert, Jacqueline. Design of a new and highly effective chiral auxiliary for Diels-Alder reaction of 1-aminodiene.. In: The Journal of organic chemistry, Vol. 68, no. 25, p. 9809-12 (2003). doi:10.1021/jo0302049.
2003
Robiette, Raphaël ; Defacqz, N ; Stofferis, J ; Marchand-Brynaert, Jacqueline. [4+2] Cycloaddition of 1-aminodienes and 2-substituted vinylphosphonates: application to asymmetric synthesis of 3-amino-5-phosphono-1-cyclohexene derivatives. In: Tetrahedron, Vol. 59, no. 23, p. 4167-4175 (2003). doi:10.1016/S0040-4020(03)00580-5.
2002
Robiette, Raphaël ; Marchand-Brynaert, Jacqueline ; Peeters, Daniel. Influence of diene substitution on transition state stabilization in Diels-Alder reaction.. In: The Journal of organic chemistry, Vol. 67, no. 19, p. 6823-6 (2002). doi:10.1021/jo025796u.
2002
Robiette, Raphaël ; Marchand-Brynaert, Jacqueline ; Peeters, Daniel. Theoretical study of the influence of phosphonate substituents on Diels-Alder reactions. In: Journal of Molecular Structure: THEOCHEM, Vol. 587, no. 1-3, p. 159-169 (2002). doi:10.1016/S0166-1280(02)00113-6.
2001
Robiette, Raphaël ; Marchand-Brynaert, Jacqueline. Asymmetric synthesis of beta- and gamma-amidophosphonates by Diels-Alder reaction using chiral aminodiene: theoretical and experimental study of the facial selectivity of chiral N-dienyl lactam. In: Royal Chemical Society. Journal. Perkin Transactions 2, , no. 11, p. 2155-2158 (2001). doi:10.1039/b105070m.
2014
Robiette, Raphaël ; Marchand-Brynaert, Jacqueline. Formation of four-membered heterocycles. In: Paul Knochel et Gary A. Molander, Comprehensive Organic Synthesis, 2nd Edition, Vol. 5, 2nd Ed., Elsevier, 2014, 85-128 p.. 0080977421. doi:10.1016/B978-0-08-097742-3.00503-6.
2001
Marchand-Brynaert, Jacqueline ; Defacqz, Nathalie ; Robiette, Raphaël. [4+2] Cycloaddition of phosphoryl-substituted dienes and dienophiles with a view of preparing aminophosphonic acid derivatives. In: Pandalai S.G., Recent Research Developments in Organic Chemistry. vol 5, Transworld Research Network: Trivandrum, 2001. 9788178950068.